Question 1 of 5 · Chemical Reactions & Bonding
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Hydrogenation of vegetable oils using nickel as a catalyst is an example of:

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Answer: Option A — Addition reaction

Detailed Solution

In an addition reaction, two or more molecules combine to form a single larger product, without losing any atoms. Addition reactions are typical of unsaturated compounds, which have double or triple bonds between carbon atoms. During the reaction, the double or triple bond opens up, and new atoms attach to the carbon atoms.

Vegetable oils, such as groundnut oil, cottonseed oil and soyabean oil, contain unsaturated fatty acids with carbon-carbon double bonds. This is why they are liquid at room temperature. In hydrogenation, hydrogen gas is passed through the heated oil in the presence of finely divided nickel (or palladium) as a catalyst. The hydrogen atoms add across the double bonds, turning them into single bonds. The oil becomes saturated and changes into a semi-solid fat. This is how vanaspati ghee (a hydrogenated vegetable fat) and margarine are made.

The reaction can be shown simply as: R-CH=CH-R + H2 (nickel catalyst) → R-CH2-CH2-R.

Hydrogenation makes fats last longer without going rancid and gives them a texture like butter or ghee. However, partial hydrogenation produces trans fats, which raise "bad" (LDL) cholesterol and increase the risk of heart disease. For this reason, the Food Safety and Standards Authority of India (FSSAI) has limited trans fats in oils and fats to 2% from 2022. Doctors advise that oils with unsaturated fats are healthier than saturated animal fats.

Why not the other options?

  • ✗Substitution reactions replace one atom or group with another; they are typical of saturated compounds such as alkanes (for example, the chlorination of methane in sunlight).
  • ✗Decomposition reactions break one compound into simpler substances.
  • ✗Displacement reactions occur when a more reactive element displaces a less reactive one from its compound.

Quick tip

Remember: Hydrogenation of oils = addition reaction, nickel catalyst, gives vanaspati ghee; unsaturated compounds = addition; saturated compounds = substitution.

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Chemical Reactions & Bonding — Preparation

This question tests your understanding of Chemical Reactions & Bonding, a key topic in the General Knowledge section. The detailed solution above uses a step-by-step approach to show the reasoning, and where available, a shortcut that helps you solve similar questions in under 90 seconds during the actual exam.

This topic covers chemical bonding (ionic, covalent and metallic bonds), types of chemical reactions (combination, decomposition, displacement, double displacement, oxidation and reduction, and redox), catalysts, the rate of reactions, and everyday examples such as corrosion and rancidity. Exams ask which type of reaction an example shows, what a catalyst does (it changes the rate of a reaction without being used up), and how corrosion and rancidity can be prevented. Remember that oxidation is the gain of oxygen or loss of electrons, reduction is the opposite, and a redox reaction involves both at the same time. Practise the chemical reactions and bonding questions below, written in the style of the general awareness sections of exams such as SSC, banking, railways, CUET GAT, MAH CET and CLAT. Each question comes with a detailed explanation that adds related facts, so every question helps you revise more than one point.