Question 4 of 5 · Metals, Non-metals & Metallurgy
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Metal oxides that react with both acids and bases to produce salt and water are called:

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Answer: Option D — Amphoteric oxides

Detailed Solution

Oxides are compounds formed when elements combine with oxygen. They are classified according to how they react with acids and bases:

Basic oxides: most metal oxides are basic. They react with acids to form salt and water. Examples: sodium oxide (Na2O), calcium oxide (CaO) and magnesium oxide (MgO). Soluble basic oxides, such as Na2O, dissolve in water to form alkalis.

Acidic oxides: most non-metal oxides are acidic. They react with bases to form salt and water, and many dissolve in water to form acids. Examples: carbon dioxide (CO2), sulphur dioxide (SO2), sulphur trioxide (SO3) and phosphorus pentoxide (P2O5).

Amphoteric oxides: these oxides show both acidic and basic properties. They react with acids as well as with bases to form salt and water. The word "amphoteric" comes from the Greek word "amphoteros", meaning "both".

Neutral oxides: these show neither acidic nor basic properties. Examples: carbon monoxide (CO), nitrous oxide (N2O), nitric oxide (NO) and water (H2O).

Common examples of amphoteric oxides are aluminium oxide (Al2O3) and zinc oxide (ZnO). Lead oxide and tin oxide are also amphoteric.

For example, aluminium oxide reacts:

  • With hydrochloric acid (acting as a base): Al2O3 + 6HCl → 2AlCl3 + 3H2O.
  • With sodium hydroxide (acting as an acid): Al2O3 + 2NaOH → 2NaAlO2 (sodium aluminate) + H2O.
  • Similarly, zinc oxide reacts with hydrochloric acid to form zinc chloride, and with sodium hydroxide to form sodium zincate.
  • This amphoteric nature of aluminium oxide is used in the Bayer process to extract pure alumina from bauxite ore, by dissolving it in sodium hydroxide.
  • Water is also described as amphoteric (or amphiprotic), because it can act as both an acid and a base.

Why not the other options?

  • ✗Basic oxides, such as CaO and Na2O, react only with acids.
  • ✗Acidic oxides, such as CO2 and SO2, react only with bases.
  • ✗Neutral oxides, such as CO and N2O, react with neither.

Quick tip

Remember: Amphoteric oxides = Al2O3 and ZnO (react with both acids and bases); metal oxides = basic; non-metal oxides = acidic; CO, NO and N2O = neutral.

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Metals, Non-metals & Metallurgy — Preparation

This question tests your understanding of Metals, Non-metals & Metallurgy, a key topic in the General Knowledge section. The detailed solution above uses a step-by-step approach to show the reasoning, and where available, a shortcut that helps you solve similar questions in under 90 seconds during the actual exam.

This topic covers the properties of metals and non-metals, the reactivity series, ores and minerals of common metals, metallurgy (concentration, roasting, calcination and refining), alloys and their compositions, and the corrosion of metals. Common questions ask about the ore of a metal (bauxite for aluminium and haematite for iron), the composition of alloys (brass is copper and zinc, and bronze is copper and tin), the best conductor of electricity (silver), and the most abundant metal in the Earth's crust (aluminium). Galvanisation coats iron with zinc to prevent rusting. Practise the metals, non-metals and metallurgy questions below, written in the style of the general awareness sections of exams such as SSC, banking, railways, CUET GAT, MAH CET and CLAT. Each question comes with a detailed explanation that adds related facts, so every question helps you revise more than one point.