Question 5 of 5 Β· Metals, Non-metals & Metallurgy
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SSC Β· Railway

Potassium and sodium react violently with:

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Answer: Option A β€” Cold water

Detailed Solution

Sodium (Na) and potassium (K) are alkali metals, found in Group 1 of the periodic table. They are among the most reactive metals. Each has only one electron in its outermost shell, which it loses very easily to form a positive ion.

When sodium or potassium is put into cold water, it reacts vigorously. It forms a metal hydroxide (an alkali) and hydrogen gas, and a large amount of heat is released (the reaction is highly exothermic):

2Na + 2H2O β†’ 2NaOH + H2 + heat

2K + 2H2O β†’ 2KOH + H2 + heat

The heat produced is so great that the hydrogen gas catches fire. Sodium melts into a silvery ball that darts around on the surface of the water, and the hydrogen may burn with a yellow flame. Potassium reacts even more violently, and the hydrogen catches fire immediately with a lilac (violet) flame.

Because they react so readily with water and with oxygen in the air, sodium and potassium are stored under kerosene (paraffin oil) to prevent contact with air and moisture. They are soft enough to be cut with a knife.

The reactivity of metals with water decreases down the reactivity series:

  • Potassium, sodium and calcium react with cold water (calcium less violently; it floats because of hydrogen bubbles sticking to it).
  • Magnesium reacts very slowly with cold water but quickly with hot water.
  • Aluminium, zinc and iron do not react with cold or hot water but react with steam to form metal oxides and hydrogen.
  • Lead, copper, silver and gold do not react with water at all.
  • Reactivity of alkali metals increases down the group: lithium < sodium < potassium < rubidium < caesium, because the outer electron is farther from the nucleus and more easily lost.

Why not the other options?

  • βœ—Hot water only describes magnesium.
  • βœ—Steam only describes metals such as aluminium, zinc and iron.
  • βœ—Neither describes metals such as copper, silver and gold.

Quick tip

Remember: Na and K react violently with cold water (stored in kerosene); Mg with hot water; Al, Zn and Fe with steam; Cu, Ag and Au do not react with water.

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Metals, Non-metals & Metallurgy β€” Preparation

This question tests your understanding of Metals, Non-metals & Metallurgy, a key topic in the General Knowledge section. The detailed solution above uses a step-by-step approach to show the reasoning, and where available, a shortcut that helps you solve similar questions in under 90 seconds during the actual exam.

This topic covers the properties of metals and non-metals, the reactivity series, ores and minerals of common metals, metallurgy (concentration, roasting, calcination and refining), alloys and their compositions, and the corrosion of metals. Common questions ask about the ore of a metal (bauxite for aluminium and haematite for iron), the composition of alloys (brass is copper and zinc, and bronze is copper and tin), the best conductor of electricity (silver), and the most abundant metal in the Earth's crust (aluminium). Galvanisation coats iron with zinc to prevent rusting. Practise the metals, non-metals and metallurgy questions below, written in the style of the general awareness sections of exams such as SSC, banking, railways, CUET GAT, MAH CET and CLAT. Each question comes with a detailed explanation that adds related facts, so every question helps you revise more than one point.